2024

D-A-D push-pull

Resolution of 9,10-Diketo[7]helicene and Its Use in One-Step Preparation of Helicene-Based D–A–D Push–Pull Systems

M. Kos, T. Beránek, I. Císařová, P. Cuřínová, J. Žádný, J. Storch, V. Církva, M. Jakubec, J. Org. Chem., 2024, 89, 11, 7495.

2023

DNA-binding

Hexahelicene DNA-binding: Minor groove selectivity, semi-intercalation and chiral recognition

J. Vacek, M. Zatloukalová, E. Bartheldyová, D. Řeha, B. Minofar, K. Bednárová, D. Renciuk, J. Coufal, M. Fojta, J. Žádný, A. Gessini, B. Rossi, J. Storch, M. Kabeláč, Int. J. Biol. Macromol. 2023, 125905.

Charge-Transfer Complexation

Charge-Transfer Complexation: A Highly Effective Way Towards Chiral Nanoparticles Endowed by Intrinsically Chiral Helicene and Enantioselective SERS Detection

O. Guselnikova, R. Elashnikov, V. Švorčík, K. Záruba, M. Jakubec, J. Žádný, J. Storch, O. Lyutakov, Sens. Actuators B Chem., 2023, 134332.

2D Ti3C2Tx Flakes

Chiral Plasmonic Response of 2D Ti3C2Tx Flakes: Realization and Applications

A. Olshtrem, I. Panov, S. Chertopalov, K. Záruba, B. Vokatá, P. Sajdl, J. Lancok, J. Storch, V. Církva, V. Švorčík, M. Kartau, A. S. Karimullah, J. Váňa, O. Lyutakov, Adv. Funct. Mater. 2023, 2212786.

Push-Pull Systems

Modification of optical properties in helicenes via construction of phosphine oxide-based push-pull systems

T. Beránek, M. Kos, L. Váňa, I. Císařová, J. Sýkora, J. Storch, V. Církva, M. Jakubec, Dyes Pigm. 2023, 210, 111039.

2022

2-Phospha[7]helicene

Synthesis of 2-Phospha[7]helicene, a Helicene with a Terminal Phosphinine Ring

T. Beránek, M. Jakubec, J. Sýkora, I. Císařová, J. Žádný, J. Storch, Org. Lett. 2022, 24, 26, 4756–4761.

Aza[n]helicenes (n = 4-7)

Synthesis of Aza[n]helicenes (n = 4-7) via Photocyclodehydrochlorination of 1-Chloro-N-aryl-2-naphthamides

L. Váňa, M. Jakubec, J. Sýkora, I. Císařová, J. Žádný, J. Storch, V. Církva, J. Org. Chem. 2022, 87, 11, 7150–7166.

The Photochemical Approach to Helicenes in Helicenes: Synthesis, Properties and Applications

J. Storch, J. Žádný, V. Církva, M. Jakubec, J. Hrbáč, J. Vacek, Wiley-VCH, 2022; pp 1–52.

2021

Aza[n]phenacenes (n = 4-6)

Synthesis of Aza[n]phenacenes (n = 4-6) via Photocyclodehydrochlorination of 2-Chloro-N- aryl-1-naphthamides

L. Váňa, M. Jakubec, J. Sýkora, I. Císařová, J. Storch, V. Církva, J. Org. Chem. 2021, 86, 19, 13252–13264.

Chiroplasmon-active optical fiber

Chiroplasmon-active optical fiber probe for environment chirality estimation

E. Miliutina, J. Žádný, O. Guselnikova, J. Storch, H. Walaská, A. Kushnarenko, V. Burtsev, V. Švorčík, O. Lyutakov, Sens. Actuators B Chem., 2021, 343, 130122.

Enantioenriched Ruthenium-Tris-Bipyridine Complexes

Enantioenriched Ruthenium-Tris-Bipyridine Complexes Bearing One Helical Bipyridine Ligand: Access to Fused Multihelicenic Systems and Chiroptical Redox Switches

M. Kos, R. Rodríguez, J. Storch, J. Sýkora, E. Caytan, M. Cordier, I. Císařová, N. Vanthuyne, J. A. G. Williams, J. Žádný, V. Církva, J. Crassous, Inorg. Chem. 2021, 60, 16, 11838–11851.

Flavin-Helicene Amphiphilic Hybrids

Flavin-Helicene Amphiphilic Hybrids: Synthesis, Characterization, and Preparation of Surface-Supported Films

M. Jakubec, D. Novák, M. Zatloukalová, I. Císařová, R. Cibulka, L. Favereau, J. Crassous, A. Cytryniak, R. Bilewicz, J. Hrbáč, J. Storch, J. Žádný, J. Vacek, ChemPlusChem 2021, 86, 7, 982-990.

2020

Recent Advances in Functionalizations of Helicene Backbone

Recent Advances in Functionalizations of Helicene Backbone

M. Jakubec, J. Storch, J. Org. Chem. 2020, 85, 21, 13415–13428.

Anodic Deposition of Enantiopure Helical Molecules

Chiral Electrochemistry: Anodic Deposition of Enantiopure Helical Molecules

J. Vacek, J. Žádný, J. Storch, J. Hrbáč, ChemPlusChem 2020, 85, 9, 1954-1958.

Oxidative photocyclization of aromatic schiff bases

Oxidative Photocyclization of Aromatic Schiff Bases in Synthesis of Phenanthridines and Other Aza-PAHs

M. Kos, J. Žádný, J. Storch, V. Církva, P. Cuřínová, J. Sýkora, I. Císařová, F. Kuriakose, I. V. Alabugin, Int. J. Mol. Sci. 2020, 21, 16, 5868.

Photochemical oxidation specific to distorted aromatic amines

Photochemical Oxidation Specific to Distorted Aromatic Amines Providing ortho-Diketones

M. Jakubec, S. Hansen-Troøyen, I. Císařová, J. Sýkora, J. Storch, Org. Lett. 2020, 22, 10, 3905–3910.

Redox and optically active carbohelicene layers

Redox and optically active carbohelicene layers prepared by potentiodynamic polymerization

J. Hrbáč, V. Pavelka, J. Crassous, J. Žádný, L. Fekete, J. Pokorný, P. Vanýšek, J. Storch, J. Vacek, Electrochem. Commun. 2020, 113, 106689.

Post-synthetic derivatization of graphitic carbon nitride

Post-Synthetic Derivatization of Graphitic Carbon Nitride with Methanesulfonyl Chloride: Synthesis, Characterization and Photocatalysis

P. Praus, A. Smýkalová, K. Foniok, P. Velíšek, D. Cvejn, J. Žádný, J. Storch, Nanomaterials 2020, 10, 2, 193.

Synthesis of a Helical Phosphine

Synthesis of a Helical Phosphine and a Catalytic Study of Its Palladium Complex

T. Beránek, J. Žádný, T. Strašák, J. Karban, I. Císařová, J. Sýkora, J. Storch, ACS Omega 2020, 5, 1, 882–892.

Photochemical Functionalization of Helicenes

Photochemical Functionalization of Helicenes

M. Jakubec, I. Ghosh, J. Storch, B. König, Chem. Eur. J. 2020, 26, 2, 543-547.

2019

Cytotoxicity of hexahelicene

Cytotoxicity of hexahelicene and its effect on the aryl hydrocarbon receptor pathway

J. Vrba, L. Roubalová, V. Církva, J. Storch, J. Vacek, Toxicol. In Vitro 2019, 57, 105-109.

Helicene-SPP-Based Chiral Plasmonic Hybrid Structure

Helicene-SPP-Based Chiral Plasmonic Hybrid Structure: Toward Direct Enantiomers SERS Discrimination

Y. Kalachyova, O. Guselnikova, R. Elashnikov, I. Panov, J. Žádný, V. Církva, J. Storch, J. Sýkora, K. Záruba, V. Švorčík, O. Lyutakov, ACS Appl. Mater. Interfaces 2019, 11, 1, 1555–1562.

Preparation and Physicochemical Properties of [6]Helicenes

Preparation and Physicochemical Properties of [6]Helicenes Fluorinated at Terminal Rings

V. Církva, P. Jakubík, T. Strašák, J. Hrbáč, J. Sýkora, I. Císařová, J. Vacek, J. Žádný, J. Storch, J. Org. Chem. 2019, 84, 4, 1980–1993.

2018

Anodic Deposition of Enantiopure Hexahelicene Layers

Anodic Deposition of Enantiopure Hexahelicene Layers

J. Vacek, J. Hrbáč, T. Strašák, V. Církva, J. Sýkora, L. Fekete, J. Pokorný, J. Bulíř, M. Hromadová, J. Crassous, J. Storch, ChemElectroChem 2018, 5, 15, 2080-2088.

2-Bromo[6]helicene

2-Bromo[6]helicene as a Key Intermediate for [6]Helicene Functionalization

M. Jakubec, T. Beránek, P. Jakubík, J. Sýkora, J. Žádný, V. Církva, J. Storch, J. Org. Chem. 2018, 83, 7, 3607–3616.

2017

Electrosynthesis of [7]Helicene-Derived Polymers

Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers

J. Hrbáč, T. Strašák, L. Fekete, V. Ladányi, J. Pokorný, J. Bulíř, M. Krbal, J. Žádný, J. Storch, J. Vacek, ChemElectroChem 2017, 4, 12, 3047-3052.

Contribution to cation–π interaction of the univalent silver cation with racemic [7]helicene in the solid state

B. Klepetářová, E. Makrlík, P. Vaňura, J. Storch, Struct. Chem. 2017, 28, 873–877.

Internal dynamics in helical molecules

Internal dynamics in helical molecules studied by X-ray diffraction, NMR spectroscopy and DFT calculations

M. Dračínský, J. Storch, V. Církva, I. Císařová, J. Sýkora, Phys. Chem. Chem. Phys. 2017, 19, 2900-2907.

P-Doping of graphene in hybrid materials

P-Doping of graphene in hybrid materials with 3,10-diazapicenium dications

A. Roth, T. A. Schaub, U. Meinhardt, D. Thiel, J. Storch, V. Církva, P. Jakubík, D. M. Guldi, M. Kivala, Chem. Sci. 2017,8, 3494-3499.

2016

Chiral resolution of hexahelicenes

Development of separation methods for the chiral resolution of hexahelicenes

J. Storch, K. Kalíková, E. Tesařová, V. Maier, J. Vacek, J. Chromatogr. A 2016, 1476, 130-134.

Cation-π interaction of Ag +  with [6]helicene

Experimental and theoretical study on cation-π interaction of Ag+ with [6]helicene

E. Makrlík, J. Jaklová Dytrtová, P. Vaňura, I. Císařová, J. Sýkora, V. Církva, J. Storch, M. Polášek, Struct. Chem 2016, 27, 627–635.

2015

Study on cation-π interaction of the univalent silver cation    with [7]helicene

Experimental and theoretical study on cation-π interaction of the univalent silver cation with [7]helicene in the gas phase and in the solid state

E. Makrlík, B. Klepetářová, D. Sýkora, S. Böhm, P. Vaňura, J. Storch, Chem. Phys. Lett. 2015, 635, 355-359.

Cation-π interaction of Tl +  with [6]helicene

Cation-π interaction of Tl+ with [6]helicene: Experimental and DFT study

E. Makrlík, D. Sýkora, S. Böhm, P. Vaňura, V. Církva, J. Storch, M. Polášek, J. Mol. Struct. 2015, 1100, 150-153.

Cation-π interaction of Ag +  with [6]helicene

Cation-π interaction of Ag+ with [6]helicene: An experimental and theoretical study

E. Makrlík, J. Jaklová Dytrtová, P. Vaňura, J. Sýkora, V. Církva, J. Storch, Chem. Phys. Lett. 2015, 633, 105-108.

[6]Helicene as a novel molecular tweezer

[6]Helicene as a novel molecular tweezer for the univalent silver cation: Experimental and theoretical study

B. Klepetářová, E. Makrlík, J. Jaklová Dytrtová, S. Böhm, P. Vaňura, J. Storch, J. Mol. Struct. 2015, 1097, 124-128.

Helicene-based imidazolium salt and its application

Synthesis and Characterization of a Helicene-Based Imidazolium Salt and Its Application in Organic Molecular Electronics

J. Storch, J. Žádný, T. Strašák, M. Kubala, J. Sýkora, M. Dušek, V. Církva, P. Matějka, M. Krbal, J. Vacek, Chem. Eur. J. 2015, 21, 6, 2343-2347.

Preliminary Soil and Aquatic Ecotoxicity Evaluation of [6]Helicene

T. Sovová, J. Storch, M. Bernard, L. Červenková Šťastná, V. Církva, V. Bartůněk, H. Palková, V. Kočí, Pol. J. Environ. Stud. 2015, 24, 5, 2329–2334.

2014

Immobilization of helicene onto carbon substrates

Immobilization of helicene onto carbon substrates through electropolymerization of [7]helicenyl-thiophene

J. Hrbáč, J. Storch, V. Halouzka, V. Církva, P. Matějka, J. Vacek, RSC Adv. 2014, 4, 46102-46105.

2013

9-bromo[7]helicene reactivity

Exploration of 9-bromo[7]helicene reactivity

J. Žádný, P. Velíšek, M. Jakubec, J. Sýkora, V. Církva, J. Storch, Tetrahedron 2013, 69, 30, 6213-6218.